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Ian Howard
Dr. Ian Howard
Advanced Materials and Optical Spectroscopy

Phone: +49 721 608-28398
ian howardWli3∂kit edu

Staff webpage

Bryce S. Richards
Prof. Dr. Bryce S. Richards
Member of the board of directors

Phone: +49 721 608-26562
bryce richardsIqv5∂kit edu

Staff webpage

Optical Spectroscopy

Two dedicated laser laboratories were built at the IMT in 2016, and provide the backbone for our optical spectroscopy work. Our interests range from fundamental material characterization to detailed diagnostics of device function. The common goal of these labs is to enable the engineering of devices (often based on new materials) whose macroscopic functionality relies on nano- and micro-scale material control. Our efforts in spectroscopy fall into the categories of steady-state and time-resolved techniques discussed below.

Steady-State Optical Spectroscopy

Basic Absorption/Emission Characterization

Absorption, emission, and FTIR measurements are available. The angular dependence of absorption, transmission, and reflection measurements can also be made.

Photoluminescence Quantum Yield Measurements

A home-built setup based on an integrating sphere (Labsphere) allows us to measure absolute photoluminescence quantum yields of solutions, thin films, and powders.

Continuous Wave Laser Setups

A tuneable Ti:sapphire laser with external mixing units (M squared) allows us to generate intense CW excitation beams spanning the UV to NIR (300nm – 1000 nm). Complemented by laser diodes this allows a wide variety of CW and quasi-CW laser spectroscopies to be performed.

Time-Resolved Optical Spectroscopy

Streak Camera

We use a streak camera (Hamamatsu) to perform time-resolved emission measurements on the picosecond to nanosecond timescale. The Streak camera is sensitive into the NIR (1300 nm).

Photon Counting

Time-resolved emission measurements are extended by a multichannel scaling card (Picoquant) that allows lifetime measurements from the nanosecond to millisecond time regime. A variety of detectors placed after a double monochromator (Bentham Instruments) allow the resolution of even weak signals from the visible to the NIR.

Transient Absorption

We have a Ti:sapphire amplifier system synchronized with a Q-switched pump laser to allow reaction kinetics to be monitored from hundreds of femtoseconds to several milliseconds without any gaps with a home-built transient absorption spectrometer.

Key features are:

  • 150 fs – 1 ms time range
  • 500 – 1000 nm spectral range of whitelight probe
  • Single wavelength excitation from 355 to 800 nm
  • Temperature dependent measurements possible.

Closed-Cycle Cryostat

A closed-cycle cryostat (Optistat Dry from Oxford Instruments) allows us to perform both absorption and emission measurements (time-resolved and steady-state) from room temperature to 4 K.